โซฯโฮโฮธโโ
formula sheet โฆ
All your CBSE Class 12 formulas in one place โ tap any card to drill it with Arya
Electric Charges and Fields
Electrostatic Potential and Capacitance
Current Electricity
Moving Charges and Magnetism
Magnetism and Matter
Electromagnetic Induction
Alternating Current
Electromagnetic Waves
Ray Optics and Optical Instruments
Wave Optics
Dual Nature of Radiation and Matter
Atoms
Nuclei
Semiconductor Electronics
Solutions
Electrochemistry
Chemical Kinetics
d and f Block Elements
Coordination Compounds
Haloalkanes and Haloarenes
Alcohols, Phenols and Ethers
Aldehydes, Ketones and Carboxylic Acids
Amines
Biomolecules
Relations and Functions
Inverse Trigonometric Functions
Matrices
Determinants
Continuity and Differentiability
Application of Derivatives
Integrals
Application of Integrals
Differential Equations
Vector Algebra
Three Dimensional Geometry
Linear Programming
Probability
Physics153 formulas
Ch 1 ยท Electric Charges and Fields12
Coulomb's lawโ
โ
โ
F=r2kq1โq2โโ (k = 9ร10โน N mยฒ Cโปยฒ)
board favouriteElectric field due to point chargeโ
โ
โ
E=r2kqโ or E=4ฯฮต0โr2qโ
board favouriteElectric field from force
E=q0โFโ
Electric dipole momentโ
โ
p=qร2a (direction: โq to +q)
frequently askedE on axial point of dipoleโ
โ
Eaxโ=r32kpโ (r >> a)
frequently askedE on equatorial point of dipoleโ
โ
Eeqโ=r3kpโ (r >> a)
frequently askedTorque on dipole in uniform fieldโ
โ
ฯ=pEsinฮธ or ฯ=pโรE
frequently askedGauss's lawโ
โ
โ
ฮฆEโ=โฎEโ
dA=ฮต0โqencโโ
board favouriteE due to infinite line charge (ฮป)โ
โ
E=2ฯฮต0โrฮปโ
frequently askedE due to infinite plane sheet (ฯ)โ
โ
E=2ฮต0โฯโ
frequently askedE outside uniformly charged sphere
E=4ฯฮต0โr2qโ
Electric fluxโ
โ
ฮฆ=Eโ
A=EAcosฮธ
frequently asked๐ See NCERT diagram
Diagram: Field lines (point charges, dipole, planes)
Ch 2 ยท Electrostatic Potential and Capacitance14
Electric potential due to point chargeโ
โ
V=rkqโ
frequently askedPotential difference
VAโโVBโ=qWABโโ
E and V relationโ
โ
E=โdrdVโ
frequently askedPotential due to dipole (axial)
V=r2kpcosฮธโ (axial: ฮธ=0 โ V=kp/r2)
Potential due to dipole (equatorial)
V=0 (ฮธ = 90ยฐ)
PE of system of two chargesโ
โ
U=rkq1โq2โโ
frequently askedPE of dipole in external fieldโ
โ
U=โpEcosฮธ=โpโโ
E
frequently askedCapacitance definitionโ
โ
โ
C=VQโ
board favouriteParallel plate capacitorโ
โ
โ
C=dฮต0โAโ
board favouriteWith dielectric slab (thickness t)โ
โ
C=dโt+t/Kฮต0โAโ
frequently askedCapacitors in seriesโ
โ
โ
C1โ=C1โ1โ+C2โ1โ+C3โ1โ
board favouriteCapacitors in parallelโ
โ
โ
C=C1โ+C2โ+C3โ
board favouriteEnergy stored in capacitorโ
โ
โ
U=21โCV2=2CQ2โ=2QVโ
board favouriteEnergy density in electric fieldโ
โ
u=21โฮต0โE2
frequently asked๐ See NCERT diagram
Diagram: Equipotential surfaces, parallel plate capacitor
Ch 3 ยท Current Electricity16
Electric currentโ
โ
I=tQโ=nAevdโ
frequently askedOhm's lawโ
โ
โ
V=IR
board favouriteResistance from geometryโ
โ
โ
R=AฯLโ
board favouriteTemperature dependence of resistanceโ
โ
Rtโ=R0โ(1+ฮฑฮT)
frequently askedDrift velocityโ
โ
vdโ=meEฯโ=nAeIโ
frequently askedMobility
ฮผ=Evdโโ=meฯโ
Resistors in seriesโ
โ
โ
Reqโ=R1โ+R2โ+R3โ
board favouriteResistors in parallelโ
โ
โ
Reqโ1โ=R1โ1โ+R2โ1โ+R3โ1โ
board favouriteEMF and terminal voltageโ
โ
โ
V=ฮตโIr (during discharge)
board favouriteCells in seriesโ
โ
ฮตeqโ=ฮต1โ+ฮต2โ; reqโ=r1โ+r2โ
frequently askedCells in parallel (identical)โ
โ
ฮตeqโ=ฮต; reqโ=r/n
frequently askedKirchhoff's Current Law (KCL)โ
โ
โ
ฮฃIinโ=ฮฃIoutโ at junction
board favouriteKirchhoff's Voltage Law (KVL)โ
โ
โ
ฮฃV=0 around closed loop
board favouriteWheatstone bridge balance conditionโ
โ
โ
QPโ=SRโ
board favouriteElectric powerโ
โ
โ
P=VI=I2R=RV2โ
board favouriteElectrical energyโ
โ
W=VIt=I2Rt
frequently asked๐ See NCERT diagram
Diagram: Metre bridge, Potentiometer
Ch 4 ยท Moving Charges and Magnetism16
Biot-Savart lawโ
โ
โ
dB=4ฯฮผ0โโโ
r2Idlsinฮธโ
board favouriteB at centre of circular loopโ
โ
โ
B=2Rฮผ0โIโ
board favouriteB on axis of circular loopโ
โ
B=2(R2+x2)3/2ฮผ0โIR2โ
frequently askedAmpere's circuital lawโ
โ
โ
โฎBโ
dl=ฮผ0โIencโ
board favouriteB inside solenoidโ
โ
โ
B=ฮผ0โnI (n = N/L turns/metre)
board favouriteB inside toroidโ
โ
B=2ฯrฮผ0โNIโ
frequently askedB due to long straight wireโ
โ
โ
B=2ฯrฮผ0โIโ
board favouriteLorentz force on moving chargeโ
โ
โ
F=q(vรB); F=qvBsinฮธ
board favouriteForce on current-carrying conductorโ
โ
โ
F=BILsinฮธ; F=ILรB
board favouriteForce per unit length between two wiresโ
โ
LFโ=2ฯdฮผ0โI1โI2โโ
frequently askedTorque on current loop in B fieldโ
โ
ฯ=NIABsinฮธ; ฯ=MรB
frequently askedMagnetic moment of current loopโ
โ
M=NIA
frequently askedRadius of circular motion in B fieldโ
โ
r=qBmvโ
frequently askedTime period in cyclotronโ
โ
T=qB2ฯmโ; ฮฝ=2ฯmqBโ
frequently askedGalvanometer โ ammeter (shunt S)โ
โ
S=IโIgโIgโGโ
frequently askedGalvanometer โ voltmeter (series R)โ
โ
R=IgโVโโG
frequently askedCh 5 ยท Magnetism and Matter9
Bar magnet: B on axial pointโ
โ
B=4ฯฮผ0โโโ
r32Mโ
frequently askedBar magnet: B on equatorial pointโ
โ
B=4ฯฮผ0โโโ
r3Mโ
frequently askedTorque on bar magnet in fieldโ
โ
ฯ=MBsinฮธ=MรB
frequently askedPE of bar magnet in external field
U=โMBcosฮธ
Magnetic susceptibility
ฯ=HMโ
Relative permeability
ฮผrโ=1+ฯ
B in magnetic material
B=ฮผ0โ(H+M)=ฮผ0โฮผrโH
Curie's law (paramagnetism)โ
โ
M=TCBโ (C = Curie constant)
frequently askedEarth's magnetic field componentsโ
โ
Bvโ=Bsinฮด; BHโ=Bcosฮด
frequently asked๐ See NCERT diagram
Diagram: B-H hysteresis loop
Ch 6 ยท Electromagnetic Induction9
Faraday's lawโ
โ
โ
ฮต=โdtdฮฆโ; ฮต=โNdtdฮฆโ
board favouriteMagnetic fluxโ
โ
โ
ฮฆ=Bโ
A=BAcosฮธ
board favouriteLenz's lawโ
โ
โ
Induced current opposes change causing it
board favouriteMotional EMFโ
โ
โ
ฮต=Bvl
board favouriteSelf-inductance (flux linkage)โ
โ
Nฮฆ=LI โ ฮต=โLdtdIโ
frequently askedSelf-inductance of solenoidโ
โ
L=ฮผ0โn2Al=lฮผ0โN2Aโ
frequently askedMutual inductanceโ
โ
ฮต2โ=โMdtdI1โโ
frequently askedEnergy stored in inductorโ
โ
โ
U=21โLI2
board favouritePeak EMF in AC generatorโ
โ
ฮต=NBAฯsinฯt=ฮต0โsinฯt
frequently askedCh 7 ยท Alternating Current12
Instantaneous values & RMSโ
โ
โ
e=E0โsinฯt; Ermsโ=2โE0โโ; Irmsโ=2โI0โโ
board favouriteInductive reactanceโ
โ
โ
XLโ=ฯL=2ฯfL (unit: ฮฉ)
board favouriteCapacitive reactanceโ
โ
โ
XCโ=ฯC1โ=2ฯfC1โ (unit: ฮฉ)
board favouriteImpedance of series LCRโ
โ
โ
Z=R2+(XLโโXCโ)2โ
board favouritePhase angle ฯโ
โ
โ
tanฯ=RXLโโXCโโ
board favouriteResonance conditionโ
โ
โ
XLโ=XCโ โ ฯ0โ=LCโ1โ
board favouriteResonant frequencyโ
โ
โ
f0โ=2ฯLCโ1โ
board favouriteAverage power in AC circuitโ
โ
โ
P=Ermsโโ
Irmsโโ
cosฯ=Irms2โโ
R
board favouritePower factorโ
โ
cosฯ=ZRโ
frequently askedQuality factor (Q-factor)โ
โ
Q=Rฯ0โLโ=ฯ0โCR1โ=R1โCLโโ
frequently askedTransformer turns ratioโ
โ
โ
V1โV2โโ=N1โN2โโ=I2โI1โโ
board favouriteTransformer efficiencyโ
โ
ฮท=PinโPoutโโ=V1โI1โV2โI2โโ
frequently asked๐ See NCERT diagram
Diagram: Phasor diagrams, resonance curve
Ch 8 ยท Electromagnetic Waves6
Speed of EM waves in vacuumโ
โ
c=ฮผ0โฮต0โโ1โ=3ร108 m/s
frequently askedSpeed in a medium
v=ฮผฮตโ1โ=ncโ
E and B amplitudesโ
โ
B0โE0โโ=c
frequently askedDisplacement currentโ
โ
Idโ=ฮต0โdtdฮฆEโโ
frequently askedEnergy density of EM wave
u=21โฮต0โE2+2ฮผ0โB2โ
Generalised Ampere's lawโ
โ
โฎBโ
dl=ฮผ0โ(Icโ+Idโ)
frequently asked๐ See NCERT diagram
Diagram: Eโ โฅ Bโ โฅ vโ, EM spectrum
Ch 9 ยท Ray Optics and Optical Instruments15
Mirror formulaโ
โ
โ
v1โ+u1โ=f1โ; f=2Rโ
board favouriteMagnification (mirror)โ
โ
โ
m=โuvโ=hhโฒโ
board favouriteSnell's law of refractionโ
โ
โ
n1โsinฮธ1โ=n2โsinฮธ2โ
board favouriteCritical angle for TIRโ
โ
โ
sinC=n1โn2โโ (nโ > nโ)
board favouriteLens formulaโ
โ
โ
v1โโu1โ=f1โ
board favouriteMagnification (lens)โ
โ
m=uvโ=hhโฒโ
frequently askedLens maker's formulaโ
โ
โ
f1โ=(nโ1)[R1โ1โโR2โ1โ]
board favouritePower of a lensโ
โ
P=f(m)1โ [unit: dioptre, D]
frequently askedLenses in contact (equivalent)โ
โ
f1โ=f1โ1โ+f2โ1โ; P=P1โ+P2โ
frequently askedRefraction at spherical surfaceโ
โ
vn2โโโun1โโ=Rn2โโn1โโ
frequently askedPrism: angle of deviationโ
โ
ฮด=(i+e)โA
frequently askedPrism: refractive index (min deviation)โ
โ
โ
n=sin(2Aโ)sin(2A+Dโ)โ
board favouriteSimple microscope magnificationโ
โ
m=1+fDโ (D = 25 cm)
frequently askedCompound microscope magnificationโ
โ
M=โf0โLโร(1+feโDโ)
frequently askedAstronomical telescope magnificationโ
โ
M=โfeโf0โโ
frequently asked๐ See NCERT diagram
Diagram: Mirror, lens, prism, TIR, telescope ray diagrams
Ch 10 ยท Wave Optics9
Constructive interference (bright fringe)โ
โ
โ
ฮx=nฮป (n = 0, 1, 2, โฆ)
board favouriteDestructive interference (dark fringe)โ
โ
โ
ฮx=2(2nโ1)ฮปโ
board favouriteYDSE: fringe width ฮฒโ
โ
โ
ฮฒ=dฮปDโ
board favouritenth bright fringe positionโ
โ
ynโ=dnฮปDโ
frequently askednth dark fringe positionโ
โ
ynโ=2d(2nโ1)ฮปDโ
frequently askedSingle slit: first minimaโ
โ
asinฮธ=ฮป โ y=aฮปDโ
frequently askedAngular width of central maximumโ
โ
2ฮธ=a2ฮปโ
frequently askedMalus's law (polarisation)โ
โ
โ
I=I0โcos2ฮธ
board favouriteBrewster's angleโ
โ
taniBโ=n
frequently asked๐ See NCERT diagram
Diagram: YDSE setup, single slit diffraction pattern
Ch 11 ยท Dual Nature of Radiation and Matter8
Photon energyโ
โ
โ
E=hf=ฮปhcโ
board favouritePhoton momentumโ
โ
p=ฮปhโ=cEโ
frequently askedEinstein's photoelectric equationโ
โ
โ
KEmaxโ=hfโฯ=h(fโf0โ)
board favouriteWork functionโ
โ
ฯ=hf0โ (fโ = threshold frequency)
frequently askedStopping potentialโ
โ
eV0โ=KEmaxโ
frequently askedde Broglie wavelengthโ
โ
โ
ฮป=mvhโ=phโ
board favouritede Broglie ฮป for accelerated electronโ
โ
โ
ฮป=2meVโhโ
board favouritede Broglie ฮป in terms of KEโ
โ
ฮป=2mโ
KEโhโ
frequently asked๐ See NCERT diagram
Diagram: Photoelectric effect, KE vs f graph
Ch 12 ยท Atoms6
Bohr's radius of nth orbitโ
โ
โ
rnโ=Zn2a0โโ (aโ = 0.529 ร
)
board favouriteVelocity in nth orbitโ
โ
vnโ=n2.18ร106Zโ m/s
frequently askedEnergy of electron in nth orbitโ
โ
โ
Enโ=โn213.6Z2โ eV
board favouriteFrequency of emitted photonโ
โ
hฮฝ=E2โโE1โ (Eโ > Eโ)
frequently askedRydberg formulaโ
โ
โ
ฮป1โ=RZ2(n12โ1โโn22โ1โ) [R = 1.097ร10โท mโปยน]
board favouriteBohr's angular momentum conditionโ
โ
mvr=2ฯnhโ=nโ
frequently asked๐ See NCERT diagram
Diagram: Rutherford/Bohr model, hydrogen spectrum series
Ch 13 ยท Nuclei10
Nuclear radiusโ
โ
R=R0โA1/3 (Rโ = 1.2ร10โปยนโต m = 1.2 fm)
frequently askedMass defectโ
โ
โ
ฮm=[Zmpโ+(AโZ)mnโ]โMnucleusโ
board favouriteBinding energyโ
โ
โ
BE=ฮmรc2=ฮmร931.5 MeV/u
board favouriteBinding energy per nucleonโ
โ
BE/A
frequently askedRadioactive decay lawโ
โ
โ
N=N0โeโฮปt
board favouriteHalf-lifeโ
โ
โ
T1/2โ=ฮป0.693โ
board favouriteActivityโ
โ
โ
A=ฮปN=A0โeโฮปt [unit: Becquerel]
board favouriteMean life (average life)โ
โ
ฯ=ฮป1โ=0.693T1/2โโ
frequently askedMass-energy equivalenceโ
โ
โ
E=mc2
board favouriteQ-value of nuclear reactionโ
โ
Q=(mreactantsโโmproductsโ)c2
frequently asked๐ See NCERT diagram
Diagram: BE/A vs A curve, N vs t decay graph
Ch 14 ยท Semiconductor Electronics11
Intrinsic carrier concentrationโ
โ
ni2โ=neโรnhโ
frequently askedConductivity of semiconductor
ฯ=niโe(ฮผeโ+ฮผhโ)
Diode current equation
I=I0โ(eeV/kBโTโ1)
Transistor current relationโ
โ
โ
IEโ=IBโ+ICโ
board favouriteCurrent gain ฮฑ (CB configuration)โ
โ
โ
ฮฑ=IEโICโโ (< 1)
board favouriteCurrent gain ฮฒ (CE configuration)โ
โ
โ
ฮฒ=IBโICโโ; ฮฒ=1โฮฑฮฑโ
board favouriteRelation between ฮฑ and ฮฒโ
โ
โ
ฮฑ=1+ฮฒฮฒโ; ฮฒ=1โฮฑฮฑโ
board favouriteVoltage gain of CE amplifierโ
โ
Avโ=โฮฒรRBโRCโโ
frequently askedDe Morgan's theoremsโ
โ
โ
(Aโ
B)โฒ=Aโฒ+Bโฒ; (A+B)โฒ=Aโฒโ
Bโฒ
board favouriteNAND gate outputโ
โ
Y=(Aโ
B)โฒ
frequently askedNOR gate outputโ
โ
Y=(A+B)โฒ
frequently asked๐ See NCERT diagram
Diagram: Energy bands, p-n junction, transistor circuits
Chemistry90 formulas
Ch 1 ยท Solutions9
Raoult's law (ideal solution)โ
โ
โ
pAโ=xAโโ
pAโโ (Raoult's law)
board favouriteTotal pressure of ideal binary solutionโ
โ
โ
Ptotalโ=xAโpAโโ+xBโpBโโ
board favouriteHenry's law (gas in liquid)โ
โ
p=KHโโ
x (K_H = Henry's constant)
frequently askedElevation in boiling pointโ
โ
โ
ฮTbโ=Kbโโ
m (Kb = molal elevation constant)
board favouriteDepression in freezing pointโ
โ
โ
ฮTfโ=Kfโโ
m (Kf = molal depression constant)
board favouriteOsmotic pressureโ
โ
โ
ฯ=CRT=VnโRT
board favouritevan't Hoff factorโ
โ
i = observed colligative property / calculated value (no assoc./dissoc.)
frequently askedMolalityโ
โ
m=kgย ofย solventmolesย ofย soluteโ
frequently askedMole fractionโ
โ
xAโ=nAโ+nBโnAโโ
frequently asked๐ See NCERT diagram
Diagram: P-x graph (ideal, +ve, โve deviation), osmosis setup
Ch 2 ยท Electrochemistry10
Standard cell potentialโ
โ
โ
Ecellโโ=EcathodeโโโEanodeโโ
board favouriteNernst equationโ
โ
โ
Ecellโ=Ecellโโโn0.0592โlogQ (at 25ยฐC)
board favouriteGibbs energy and cell potentialโ
โ
โ
ฮGโ=โnFEcellโโ
board favouriteEquilibrium constant from Eยฐโ
โ
โ
logK=0.0592nEcellโโโ
board favouriteKohlrausch's law (strong electrolyte)โ
โ
ฮmโ=ฮmโโโbcโ
frequently askedMolar conductivity at infinite dilutionโ
โ
ฮmโโ=ฮฝ+โฮป+โโ+ฮฝโโฮปโโโ
frequently askedDegree of dissociation from conductivityโ
โ
ฮฑ=ฮmโโฮmโโ
frequently askedFaraday's first law of electrolysisโ
โ
โ
m=ZIt=nFMโโ
It
board favouriteFaraday's second lawโ
โ
m2โm1โโ=E2โE1โโ (E = equivalent weight)
frequently askedElectrochemical equivalent Z
Z=nFMโ
๐ See NCERT diagram
Diagram: Daniell cell, electrolytic cell, lead storage battery
Ch 3 ยท Chemical Kinetics8
Rate of reactionโ
โ
Rate=โa1โdtd[A]โ=+b1โdtd[B]โ
frequently askedRate lawโ
โ
โ
Rate=k[A]m[B]n (m, n = order w.r.t. A, B)
board favouriteZero order: integrated rate lawโ
โ
[A]=[A]0โโkt; t1/2โ=2k[A]0โโ
frequently askedFirst order: integrated rate lawโ
โ
โ
ln[A]=ln[A]0โโkt; t1/2โ=k0.693โ
board favouriteFirst order k from concentrationโ
โ
โ
k=t2.303โlog[A][A]0โโ
board favouriteSecond order: integrated rate lawโ
โ
[A]1โ=[A]0โ1โ+kt; t1/2โ=k[A]0โ1โ
frequently askedArrhenius equationโ
โ
โ
k=AeโEaโ/RT or lnk=lnAโRTEaโโ
board favouriteArrhenius: k from two temperaturesโ
โ
โ
logk1โk2โโ=2.303REaโโ(T1โ1โโT2โ1โ)
board favourite๐ See NCERT diagram
Diagram: PE vs reaction coordinate (Ea), concentration vs time plots
Ch 4 ยท d and f Block Elements9
Electronic config of transition metals (general)โ
โ
(nโ1)d1โ10ns1โ2
frequently askedOxidation states: variable due to d-electronsโ
โ
e.g. Mn: +2,+3,+4,+6,+7
frequently askedIonisation enthalpy trend across 3d series
Generally increases (irregularities at Cr, Cu)
Atomic radius trend across 3d series
Decreases slightly then levels off
Crystal field splitting: octahedral
ฮoโ = energy gap between tโg and eแต sets
Crystal field splitting: tetrahedral
ฮtโ=94โฮoโ
Magnetic moment formulaโ
โ
โ
ฮผ=n(n+2)โ BM (n = unpaired electrons)
board favouriteKMnOโ: structure and oxidising actionโ
โ
MnOโโป โ Mnยฒโบ (acidic); MnOโโป โ MnOโ (neutral/basic)
frequently askedKโCrโOโ: dichromate structure and reactionsโ
โ
CrโOโยฒโป + 14Hโบ + 6eโป โ 2Crยณโบ + 7HโO
frequently askedCh 5 ยท Coordination Compounds10
Werner's theory: primary & secondary valencyโ
โ
Primary = oxidation state; Secondary = coordination number
frequently askedIUPAC naming rule order
[cation name][anion name]; ligands alphabetical
VBT: inner orbital complexes (low spin)โ
โ
Use inner (nโ1)d orbitals; diamagnetic/low spin
frequently askedVBT: outer orbital complexes (high spin)โ
โ
Use outer nd orbitals; paramagnetic/high spin
frequently askedOctahedral geometry โ hybridisationโ
โ
โ
sp3d2 or d2sp3
board favouriteTetrahedral geometry โ hybridisationโ
โ
โ
sp3
board favouriteSquare planar geometry โ hybridisationโ
โ
โ
dsp2
board favouriteGeometrical isomerism: cis and transโ
โ
cis-[Pt(NHโ)โClโ]: both Cl same side
frequently askedOptical isomerism: d and l enantiomersโ
โ
Non-superimposable mirror images; rotate plane-polarised light
frequently askedLinkage isomerism
e.g. โNOโ (nitro) vs โONO (nitrito)
๐ See NCERT diagram
Diagram: Octahedral, tetrahedral, square planar geometries
Ch 6 ยท Haloalkanes and Haloarenes8
SN1 mechanism (unimolecular)โ
โ
โ
Step 1: ionisation โ carbocation; Step 2: Nu attack; Rate = k[RX]
board favouriteSN2 mechanism (bimolecular)โ
โ
โ
One step; backside attack; Walden inversion; Rate = k[RX][Nu]
board favouriteOptical isomers: R and S configuration (CIP)โ
โ
Priorities by atomic number; R = clockwise; S = anticlockwise
frequently askedResonance of haloarenes (โI but +R effect)โ
โ
Lone pair on X delocalises into ring โ less reactive to Nu
frequently askedFinkelstein reactionโ
โ
RโCl + NaI โ RโI + NaCl (in dry acetone)
frequently askedSwarts reactionโ
โ
RโCl + AgF โ RโF + AgCl
frequently askedGrignard reagent formationโ
โ
โ
RโX + Mg โ RโMgโX (in dry ether)
board favouriteWurtz reactionโ
โ
2RโX + 2Na โ RโR + 2NaX
frequently asked๐ See NCERT diagram
Diagram: SN1 energy profile, SN2 transition state, Walden inversion
Ch 7 ยท Alcohols, Phenols and Ethers8
H-bonding in alcohols (high bp vs ethers)โ
โ
OโHยทยทยทO bonding; intermolecular; raises bp
frequently askedResonance of phenolโ
โ
โOH lone pair delocalises into ring; ring activated; acidic
frequently askedLucas test (1ยฐ, 2ยฐ, 3ยฐ alcohols)โ
โ
โ
3ยฐ โ immediate turbidity; 2ยฐ โ turbid in 5 min; 1ยฐ โ no reaction (cold)
board favouriteAcid catalysed dehydration orderโ
โ
3ยฐ > 2ยฐ > 1ยฐ (stability of carbocation)
frequently askedVictor Meyer testโ
โ
1ยฐ โ red; 2ยฐ โ blue; 3ยฐ โ colourless
frequently askedKolbe's reaction (phenol + COโ)โ
โ
Phenol + NaOH โ sodium phenoxide + COโ โ salicylate
frequently askedRiemer-Tiemann reactionโ
โ
Phenol + CHClโ + NaOH โ o-hydroxybenzaldehyde
frequently askedWilliamson synthesis (preparation of ethers)โ
โ
RโONa + R'โX โ RโOโR' + NaX
frequently askedCh 8 ยท Aldehydes, Ketones and Carboxylic Acids10
Nucleophilic addition to C=Oโ
โ
Nuโป attacks C of C=O โ tetrahedral intermediate โ product
frequently askedAldol condensationโ
โ
โ
2CHโCHO โ (NaOH) CHโCH(OH)CHโCHO โ (โHโO) CHโCH=CHCHO
board favouriteCannizzaro reaction (non-enolisable)โ
โ
2HCHO โ (NaOH) CHโOH + HCOONa
frequently askedClemmensen reductionโ
โ
C=O โ CHโ (Zn-Hg/HCl)
frequently askedWolff-Kishner reductionโ
โ
C=O โ CHโ (NHโNHโ/KOH/ฮ)
frequently askedTollens' test (silver mirror)โ
โ
โ
RCHO + 2[Ag(NHโ)โ]โบ โ RCOOโป + 2Agโ
board favouriteFehling's testโ
โ
โ
RCHO + 2Cuยฒโบ โ RCOOโป + CuโOโ (red ppt)
board favouriteIodoform test (methyl ketones)โ
โ
โ
RCOCHโ + Iโ/NaOH โ CHIโโ (yellow) + RCOONa
board favouriteHell-Volhard-Zelinsky (HVZ) reactionโ
โ
RCOOH + Brโ/(P) โ RCH(Br)COOH
frequently askedResonance of carboxylate anion (RCOOโป)
CโO bonds equivalent (1.5 bond order); charge delocalised
๐ See NCERT diagram
Diagram: Nucleophilic addition mechanism, aldol mechanism
Ch 9 ยท Amines8
Structure of amines: spยณ N with lone pairโ
โ
Pyramidal shape; lone pair responsible for basic character
frequently askedResonance of aniline (reduced basicity)โ
โ
Lone pair delocalised into ring; less available for protonation
frequently askedBasicity orderโ
โ
โ
Aliphatic: 2ยฐ > 1ยฐ > 3ยฐ > NHโ; Aromatic: NHโ > aniline
board favouriteGabriel phthalimide synthesis (primary amine)โ
โ
Phthalimide + KOH โ K-salt + RX โ N-alkyl phthalimide โ (HโNNHโ) 1ยฐ amine
frequently askedHoffmann bromamide degradationโ
โ
RCONHโ + Brโ + 4NaOH โ RNHโ + NaโCOโ + 2NaBr + 2HโO
frequently askedCarbylamine reaction (ID test for 1ยฐ amine)โ
โ
โ
RNHโ + CHClโ + 3KOH โ RNC (isocyanide, foul smell)
board favouriteDiazonium salt formation (Sandmeyer)โ
โ
โ
ArNHโ + NaNOโ + HCl โ ArNโโบClโป โ ArCl (with CuCl)
board favouriteAzo dye coupling reactionโ
โ
ArNโโบ + ArOH (alkaline) โ ArโN=NโAr (coloured azo dye)
frequently asked๐ See NCERT diagram
Diagram: Pyramidal amine, aniline resonance, diazonium coupling
Ch 10 ยท Biomolecules10
Glucose open chain structure (aldohexose)โ
โ
CHOโ(CHOH)โโCHโOH (D-glucose)
frequently askedHaworth (ring) structure of glucoseโ
โ
ฮฑ-D-glucopyranose: โOH on C1 below ring; ฮฒ: above
frequently askedFructose: ketohexose ring structure
Furanose ring (5-membered); ฮฑ and ฮฒ anomers
Disaccharide linkageโ
โ
โ
Sucrose: ฮฑ-1,ฮฒ-2 glycosidic bond (non-reducing); Maltose: ฮฑ-1,4 (reducing)
board favouritePeptide bond formationโ
โ
โ
โCOOH + HโNโ โ โCOโNHโ + HโO (condensation)
board favouriteAmino acid general structureโ
โ
HโNโCHRโCOOH (R = side chain); zwitterion at isoelectric pH
frequently askedSecondary protein structure: ฮฑ-helixโ
โ
Intramolecular H-bonds (C=OยทยทยทHโN) every 4th residue
frequently askedSecondary protein structure: ฮฒ-pleated sheet
Intermolecular H-bonds between adjacent polypeptide chains
DNA double helix base pairingโ
โ
โ
AโT (2 H-bonds); GโC (3 H-bonds); antiparallel strands
board favouriteNucleotide = base + sugar + phosphateโ
โ
Purine bases: Adenine, Guanine; Pyrimidine: Cytosine, Thymine, Uracil
frequently asked๐ See NCERT diagram
Diagram: Haworth projections, ฮฑ-helix, DNA double helix
Mathematics148 formulas
Ch 1 ยท Relations and Functions8
Reflexive relationโ
โ
aRaโaโA
frequently askedSymmetric relationโ
โ
aRbโbRaโa,bโA
frequently askedTransitive relationโ
โ
aRb&bRcโaRc
frequently askedEquivalence relationโ
โ
โ
Reflexive + Symmetric + Transitive
board favouriteOne-one (injective)โ
โ
f(x1โ)=f(x2โ)โx1โ=x2โ
frequently askedOnto (surjective)โ
โ
Range of f = Codomain
frequently askedNumber of relations from A to B
2n(A)รn(B)
Number of functions from A to B
[n(B)]n(A)
Ch 2 ยท Inverse Trigonometric Functions12
sinโปยน(โx) = โsinโปยนxโ
โ
โ
sinโ1(โx)=โsinโ1x
board favouritecosโปยน(โx) = ฯ โ cosโปยนxโ
โ
โ
cosโ1(โx)=ฯโcosโ1x
board favouritetanโปยน(โx) = โtanโปยนxโ
โ
tanโ1(โx)=โtanโ1x
frequently askedsinโปยนx + cosโปยนx = ฯ/2โ
โ
โ
sinโ1x+cosโ1x=2ฯโ,ย xโ[โ1,1]
board favouritetanโปยนx + cotโปยนx = ฯ/2โ
โ
โ
tanโ1x+cotโ1x=2ฯโ
board favouritesecโปยนx + cosecโปยนx = ฯ/2โ
โ
secโ1x+cscโ1x=2ฯโ
frequently askedtanโปยนx + tanโปยนy (|xy| < 1)โ
โ
โ
tanโ11โxyx+yโ
board favouritetanโปยนx โ tanโปยนyโ
โ
tanโ11+xyxโyโ
frequently asked2tanโปยนx (as sinโปยน and cosโปยน)โ
โ
sinโ11+x22xโ=cosโ11+x21โx2โ=2tanโ1x
frequently askedsinโปยนx = cosecโปยน(1/x)
sinโ1x=cscโ1x1โ
cosโปยนx = secโปยน(1/x)
cosโ1x=secโ1x1โ
tanโปยนx = cotโปยน(1/x) for x > 0
tanโ1x=cotโ1x1โ,ย x>0
Ch 3 ยท Matrices10
Order of matrix: m rows ร n columns
A=[aijโ]mรnโ
(Aแต)แต = Aโ
โ
(AT)T=A
frequently asked(A+B)แต = Aแต + Bแตโ
โ
(A+B)T=AT+BT
frequently asked(AB)แต = BแตAแตโ
โ
โ
(AB)T=BTAT
board favouriteSymmetric matrixโ
โ
AT=A
frequently askedSkew-symmetric matrixโ
โ
AT=โA (diagonal elements = 0)
frequently askedMatrix multiplicationโ
โ
(AB)ijโ=โkโaikโโ
bkjโ
frequently askedInverse of Aโ
โ
โ
Aโ1=โฃAโฃadj(A)โ (|A| โ 0)
board favourite(AB)โปยน = BโปยนAโปยนโ
โ
(AB)โ1=Bโ1Aโ1
frequently askedAAโปยน = AโปยนA = Iโ
โ
AAโ1=Aโ1A=I
frequently askedCh 4 ยท Determinants9
2ร2 determinantโ
โ
โ
โacโbdโโ=adโbc
board favouriteArea of triangle (coordinate geometry)โ
โ
โ
21โโฃx1โ(y2โโy3โ)+x2โ(y3โโy1โ)+x3โ(y1โโy2โ)โฃ
board favouriteAdjoint of Aโ
โ
adj(A)=[Cjiโ] (transpose of cofactor matrix)
frequently askedInverse of matrixโ
โ
โ
Aโ1=โฃAโฃadj(A)โ,ย โฃAโฃ๎ =0
board favouriteAยทadj(A) = |A|ยทIโ
โ
Aโ
adj(A)=adj(A)โ
A=โฃAโฃโ
I
frequently askedAX = B has unique solution if |A| โ 0โ
โ
X=Aโ1B
frequently asked|AB| = |A|ยท|B|โ
โ
โฃABโฃ=โฃAโฃโ
โฃBโฃ
frequently asked|kA| = kโฟ|A| for nรn matrixโ
โ
โฃkAโฃ=knโฃAโฃ
frequently asked|Aแต| = |A|
โฃATโฃ=โฃAโฃ
Ch 5 ยท Continuity and Differentiability15
Continuity at x = aโ
โ
limxโaโโf(x)=limxโa+โf(x)=f(a)
frequently askedChain ruleโ
โ
โ
dxdโ[f(g(x))]=fโฒ(g(x))โ
gโฒ(x)
board favourited/dx(sinโปยนx)โ
โ
โ
1โx2โ1โ
board favourited/dx(cosโปยนx)โ
โ
โ
โ1โx2โ1โ
board favourited/dx(tanโปยนx)โ
โ
โ
1+x21โ
board favourited/dx(cotโปยนx)โ
โ
โ1+x21โ
frequently askedd/dx(secโปยนx)โ
โ
xx2โ1โ1โ
frequently askedd/dx(cosecโปยนx)โ
โ
โxx2โ1โ1โ
frequently askedd/dx(eหฃ)โ
โ
ex
frequently askedd/dx(aหฃ)โ
โ
axlna
frequently askedd/dx(ln x)โ
โ
x1โ
frequently askedParametric differentiationโ
โ
dxdyโ=dx/dtdy/dtโ
frequently askedLogarithmic differentiationโ
โ
y=f(x)g(x)โlny=g(x)โ
lnf(x), differentiate both sides
frequently askedRolle's theoremโ
โ
โ
f(a)=f(b), f cont., f' exists โโcโ(a,b):fโฒ(c)=0
board favouriteMean Value Theorem (Lagrange)โ
โ
โ
fโฒ(c)=bโaf(b)โf(a)โ
board favouriteCh 6 ยท Application of Derivatives8
Rate of changeโ
โ
dtdyโ=dxdyโโ
dtdxโ
frequently askedIncreasing on (a,b)โ
โ
โ
fโฒ(x)>0โxโ(a,b)
board favouriteDecreasing on (a,b)โ
โ
โ
fโฒ(x)<0โxโ(a,b)
board favouriteFirst derivative test (maxima/minima)โ
โ
โ
fโฒ(c)=0; +โโ gives max; โโ+ gives min
board favouriteSecond derivative testโ
โ
โ
fโฒ(c)=0 & fโฒโฒ(c)<0 โ max; fโฒโฒ(c)>0 โ min
board favouriteEquation of tangent at (xโ,yโ)โ
โ
โ
yโy1โ=fโฒ(x1โ)(xโx1โ)
board favouriteEquation of normal at (xโ,yโ)โ
โ
yโy1โ=โfโฒ(x1โ)1โ(xโx1โ)
frequently askedSmall approximationsโ
โ
ฮyโdy=fโฒ(x)โ
ฮx
frequently askedCh 7 ยท Integrals30
โซxโฟ dxโ
โ
โ
n+1xn+1โ+C (n โ โ1)
board favouriteโซeหฃ dxโ
โ
โ
ex+C
board favouriteโซaหฃ dxโ
โ
lnaaxโ+C
frequently askedโซ(1/x) dxโ
โ
โ
lnโฃxโฃ+C
board favouriteโซsin x dxโ
โ
โ
โcosx+C
board favouriteโซcos x dxโ
โ
โ
sinx+C
board favouriteโซsecยฒx dxโ
โ
โ
tanx+C
board favouriteโซcosecยฒx dxโ
โ
โ
โcotx+C
board favouriteโซsec x tan x dxโ
โ
secx+C
frequently askedโซcosec x cot x dxโ
โ
โcscx+C
frequently askedโซtan x dxโ
โ
lnโฃsecxโฃ+C
frequently askedโซcot x dxโ
โ
lnโฃsinxโฃ+C
frequently askedโซsec x dxโ
โ
lnโฃsecx+tanxโฃ+C
frequently askedโซcosec x dxโ
โ
lnโฃcscxโcotxโฃ+C
frequently askedโซdx/(xยฒ+aยฒ)โ
โ
โ
a1โtanโ1axโ+C
board favouriteโซdx/โ(aยฒโxยฒ)โ
โ
โ
sinโ1axโ+C
board favouriteโซdx/โ(xยฒ+aยฒ)โ
โ
lnโx+x2+a2โโ+C
frequently askedโซdx/โ(xยฒโaยฒ)โ
โ
lnโx+x2โa2โโ+C
frequently askedโซdx/(xยฒโaยฒ)โ
โ
2a1โlnโx+axโaโโ+C
frequently askedโซdx/(aยฒโxยฒ)โ
โ
2a1โlnโaโxa+xโโ+C
frequently askedโซโ(aยฒโxยฒ) dxโ
โ
2xโa2โx2โ+2a2โsinโ1axโ+C
frequently askedโซโ(xยฒ+aยฒ) dx
2xโx2+a2โ+2a2โlnโx+x2+a2โโ+C
โซโ(xยฒโaยฒ) dx
2xโx2โa2โโ2a2โlnโx+x2โa2โโ+C
Integration by parts (ILATE)โ
โ
โ
โซuโ
vdx=uโ
โซvdxโโซ(uโฒโ
โซvdx)dx
board favouriteโซeหฃ[f(x)+f'(x)] dx = eหฃf(x) + Cโ
โ
โ
โซex[f(x)+fโฒ(x)]dx=exf(x)+C
board favouriteFundamental Theorem of Calculusโ
โ
โ
โซabโf(x)dx=F(b)โF(a)
board favouriteโซโแต f(x)dx = โโซแตฆโ f(x)dxโ
โ
โซabโf(x)dx=โโซbaโf(x)dx
frequently askedโซโแต = โซโแถ + โซแถแตฆโ
โ
โซabโf(x)dx=โซacโf(x)dx+โซcbโf(x)dx
frequently askedโซโแต f(x)dx = โซโแต f(aโx)dxโ
โ
โ
โซ0aโf(x)dx=โซ0aโf(aโx)dx
board favouriteEven/Odd function integral propertyโ
โ
โ
โซโaaโf(x)dx=2โซ0aโf(x)dx (even); = 0 (odd)
board favouriteCh 8 ยท Application of Integrals5
Area under curve (above x-axis)โ
โ
โ
A=โซabโf(x)dx [f(x) โฅ 0]
board favouriteArea between two curvesโ
โ
โ
A=โซabโ[f(x)โg(x)]dx [f(x) โฅ g(x)]
board favouriteArea w.r.t. y-axisโ
โ
A=โซcdโg(y)dy
frequently askedArea of full circle xยฒ+yยฒ=aยฒโ
โ
A=ฯa2
frequently askedArea of ellipse xยฒ/aยฒ+yยฒ/bยฒ=1โ
โ
A=ฯab
frequently askedCh 9 ยท Differential Equations6
Order: highest derivative present
Order = n of highest dxndnyโ
Degree: power of highest derivative
Degree = exponent of highest order derivative (polynomial in derivatives)
Variable separable methodโ
โ
โ
f(y)dy=g(x)dxโโซf(y)dy=โซg(x)dx+C
board favouriteHomogeneous DE: substitute y = vxโ
โ
โ
dxdyโ=F(xyโ) โ y = vx โ separate variables
board favouriteLinear DE: dy/dx + Py = Qโ
โ
โ
IF=eโซPdx; solution: yโ
IF=โซQโ
IFdx+C
board favouriteLinear DE in x: dx/dy + Px = Qโ
โ
IF=eโซPdy; solution: xโ
IF=โซQโ
IFdy+C
frequently askedCh 10 ยท Vector Algebra14
Magnitude of vectorโ
โ
โฃaโฃ=a12โ+a22โ+a32โโ
frequently askedUnit vectorโ
โ
a^=โฃaโฃaโ
frequently askedSection formula (internal division m:n)โ
โ
r=m+nmb+naโ
frequently askedDot (scalar) productโ
โ
โ
aโ
b=โฃaโฃโฃbโฃcosฮธ=a1โb1โ+a2โb2โ+a3โb3โ
board favouriteAngle between two vectorsโ
โ
โ
cosฮธ=โฃaโฃโฃbโฃaโ
bโ
board favouritePerpendicular vectorsโ
โ
โ
aโฅbโaโ
b=0
board favouriteCross (vector) product magnitudeโ
โ
โ
โฃaรbโฃ=โฃaโฃโฃbโฃsinฮธ
board favouriteCross product (determinant form)โ
โ
โ
aรb=โi^a1โb1โโj^โa2โb2โโk^a3โb3โโโ
board favouriteParallel vectorsโ
โ
aโฅbโaรb=0
frequently askedArea of parallelogramโ
โ
โฃaรbโฃ
frequently askedArea of triangleโ
โ
21โโฃaรbโฃ
frequently askedScalar triple productโ
โ
[abc]=aโ
(bรc)
frequently askedCoplanar vectorsโ
โ
[abc]=0
frequently askedProjection of aโ on bโโ
โ
โฃbโฃaโ
bโ
frequently askedCh 11 ยท Three Dimensional Geometry16
Direction cosines identityโ
โ
l2+m2+n2=1 (l=cosฮฑ, m=cosฮฒ, n=cosฮณ)
frequently askedDC from direction ratios a,b,cโ
โ
l=a2+b2+c2โaโ,ย m=a2+b2+c2โbโ,ย n=a2+b2+c2โcโ
frequently askedVector equation of lineโ
โ
โ
r=a+ฮปb
board favouriteCartesian equation of lineโ
โ
โ
axโx1โโ=byโy1โโ=czโz1โโ
board favouriteAngle between two linesโ
โ
โ
cosฮธ=โฃb1โโฃโฃb2โโฃโฃa1โa2โ+b1โb2โ+c1โc2โโฃโ
board favouriteLines perpendicularโ
โ
โ
a1โa2โ+b1โb2โ+c1โc2โ=0
board favouriteLines parallelโ
โ
a2โa1โโ=b2โb1โโ=c2โc1โโ
frequently askedShortest distance (skew lines)โ
โ
โ
d=โฃb1โรb2โโฃโฃ(a2โโa1โ)โ
(b1โรb2โ)โฃโ
board favouriteDistance between parallel linesโ
โ
d=โฃbโฃโฃbร(a2โโa1โ)โฃโ
frequently askedVector equation of planeโ
โ
โ
rโ
n^=d
board favouriteCartesian equation of planeโ
โ
โ
ax+by+cz=d
board favouritePlane through point with normal (a,b,c)โ
โ
โ
a(xโx1โ)+b(yโy1โ)+c(zโz1โ)=0
board favouriteDistance from point to planeโ
โ
โ
dist=a2+b2+c2โโฃax1โ+by1โ+cz1โโdโฃโ
board favouriteAngle between plane and lineโ
โ
sinฮธ=โฃbโฃโฃnโฃโฃbโ
nโฃโ
frequently askedIntercept form of planeโ
โ
axโ+byโ+czโ=1
frequently askedAngle between two planesโ
โ
โ
cosฮธ=โฃn1โโฃโฃn2โโฃโฃn1โโ
n2โโฃโ
board favouriteCh 12 ยท Linear Programming4
Objective functionโ
โ
Maximise/Minimise Z=ax+by
frequently askedFeasible region satisfies all constraintsโ
โ
Feasible region = intersection of all constraint half-planes
frequently askedCorner point theoremโ
โ
โ
Optimal Z always occurs at a corner (vertex) of feasible region
board favouriteUnbounded region: check if optimal existsโ
โ
Draw half-plane ax+by>M (or < m); if no common point, optimal exists
frequently askedCh 13 ยท Probability11
Conditional probabilityโ
โ
โ
P(AโฃB)=P(B)P(AโฉB)โ,ย P(B)๎ =0
board favouriteMultiplication theoremโ
โ
โ
P(AโฉB)=P(A)โ
P(BโฃA)=P(B)โ
P(AโฃB)
board favouriteIndependent eventsโ
โ
โ
P(AโฉB)=P(A)โ
P(B)
board favouriteTotal Probability theoremโ
โ
โ
P(A)=โiโP(Eiโ)โ
P(AโฃEiโ)
board favouriteBayes' theoremโ
โ
โ
P(EiโโฃA)=โjโP(Ejโ)P(AโฃEjโ)P(Eiโ)P(AโฃEiโ)โ
board favouriteBinomial distribution P(X = r)โ
โ
โ
(rnโ)prqnโr (q = 1โp)
board favouriteMean of Binomial distributionโ
โ
โ
ฮผ=E(X)=np
board favouriteVariance of Binomial distributionโ
โ
โ
ฯ2=npq
board favouriteStandard deviationโ
โ
ฯ=npqโ
frequently askedExpected value E(X)โ
โ
โ
E(X)=โxiโโ
P(xiโ)
board favouriteVariance Var(X)โ
โ
โ
Var(X)=E(X2)โ[E(X)]2=โxi2โP(xiโ)โ[E(X)]2
board favourite